Cyclisation reactions of N-cinnamoyl-9-aminoanthracenes.

نویسندگان

  • Frank D King
  • Abil Aliev
  • Stephen Caddick
  • Derek Tocher
چکیده

N-Cinnamoyl-9-aminoanthracenes cyclise with PPA or triflic acid to form novel 2-azahexacyclo[10.6.6.0(1,5).0(6,11).0(13,18).0(19,24)]tetracosa-6(11),7,9,13,15,17,19(24),20,22-nonaen-3-ones. In contrast, both N-cinnamoyl-N-methyl-9-(2-aminomethyl)anthracene and N-cinnamoyl-9-(2-aminoethyl)anthracene undergo an intramolecular Diels-Alder cycloaddition.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 12 20  شماره 

صفحات  -

تاریخ انتشار 2014